With cyanide, it is the cyanide ion CN- that does all the wounded. With cyanide salts such as potassium cyanide (KCl) and sodium cyanide (NaCl), the CN- ion detaches freely from the cation contained by solution - let lose to do adjectives it's damage. Where as beside organic molecules containing cyanide, the covalent bond is much stronger and won't break as efficiently, thus keeping the cyanide ion under wraps.
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